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To use this iron with 220V mains, you _CANNOT_ use just a passive plug adapter. That is dangerous.
You _can_ use a 220v to 110v step-down transformer. Make sure it is rated to > 100W continuous draw (many cheap ones that say they are rated to >100W are only rated for one minute on, 20 minutes off).
If you already have a reliable step-down transformer with a sufficiently high power rating, you are good to go.